Regenerared fibers from cellulose vs. cellulose (cotton) - What is the difference?
—> primary difference between regenerated cellulose fibers and cotton is the source of the cellulose
Regenerated fibers come from wood pulp or other plant-based sources, while cotton comes directly from the cotton plant
the manufacturing process for regenerated fibers involves more chemical processing compared to the natural growth and harvesting of cotton
In terms of their properties, cotton is known for its softness, breathability, and moisture-wicking abilities, while regenerated fibers can be made to have specific properties such as increased strength, moisture management, or thermal regulation
Tell me something about natural fibers - cotton: structure of the fiber, natural or synthetic, 2 advantages and disadvantages for sports wear
natural fiber that comes from the cotton plant
fibers are composed of cellulose, a natural polymer made of glucose units
Cotton fibers have a twisted, ribbon-like structure that gives them their characteristic strength and flexibility
Advantages (especally for sports wear):
include its high absorbency, which makes it comfortable to wear during physical activity and allows it to wick away moisture from the skin
also breathable, allowing air to circulate around the body, which can help regulate body temperature during exercise
Disadvantages (especally for sports wear):
include its tendency to retain moisture, which can cause it to become heavy and uncomfortable to wear during prolonged exercise
prone to wrinkling, which can make garments look unkempt or unprofessional
In addition, cotton fibers can break down over time with repeated use and washing, leading to a shorter lifespan for cotton sports wear compared to some synthetic alternatives
Tell me something about synthetic fibers - Nylon: structure of the fiber, natural or synthetic, 2 advantages and disadvantages for sports wear
Nylon is a synthetic fiber —> made from a polymer called polyamide, which is a type of synthetic plastic
Nylon fibers are known for their strength, durability, and resistance to abrasion. They are also lightweight, flexible, and have good elasticity.
Advantages of Nylon for sports wear:
Moisture-wicking —> low absorbency rate, which means they are excellent at wicking moisture away from the skin —> can help keep the wearer dry and comfortable during physical activity
Strength and durability —>incredibly strong and resistant to wear and tear —> can withstand repeated washing and wear without losing their shape or breaking down
Disadvantages of Nylon for sports wear:
Not breathable —> trap heat and moisture against the skin —> can be uncomfortable during prolonged periods of physical activity
Odor retention —> retain odors (can start to smell if not washed properly) —> problem for sports wear, as it may need to be washed more frequently to prevent odor buildup
name me materials that you would combine for a sports t-shirt, which should be suitable for climbing in hot temperatures. Justify your choice and also list the advantages and disadvantages that this combination could bring.
—> combination of polyester and merino wool
Polyester is a synthetic material that is known for its moisture-wicking properties, durability, and lightweight feel —> helps to keep the skin dry by pulling moisture away from the body and allowing it to evaporate quickly —> help to regulate body temperature and prevent discomfort during physical activity
Merino wool is a natural material that is known for its softness, breathability, and moisture management properties —> absorb up to 30% of its weight in moisture without feeling wet —> help to keep the skin dry and comfortable during physical activity
Additionally, merino wool has natural odor-resistant properties that can help to prevent unpleasant smells from building up
By combining polyester and merino wool, the resulting fabric can offer the benefits of both materials:
—> polyester can provide moisture-wicking and durability, while the merino wool can provide softness, breathability, and odor resistance
Advantages:
Moisture-wicking properties of polyester can help keep the skin dry and prevent discomfort during physical activity
Softness and breathability of merino wool can provide added comfort
Natural odor resistance of merino wool can help prevent unpleasant smells from building up
Durable and long-lasting fabric
Disadvantages:
Polyester is a synthetic material and may not be as environmentally friendly as natural materials
Merino wool can be more expensive compared to other materials
Merino wool may require special care during washing to maintain its properties
Fabric blend may not be suitable for cold temperatures or activities with high levels of moisture.
regenerated fibers from cellulose
Rayon (=viskose)
Lyocell (tencel) —> typ of rayon
Modal
what is the different between absorbency and absorption and adsorption in terms of assessing fibers performance?
absorbency = ability of a material to take in a liquid and hold it within its structure
measure how much liquid a material can hold relative to its own weight
Absorption = refers to the process of a liquid being taken in by a fiber
describes the quantity of liquid that has been absorbed by the fiber
Adsorption = fiber holds liquid onto its surface
—> in summary, absorbency refers to how much liquid a material can hold, absorption refers to the amount of liquid that has been taken in, and adsorption refers to the ability of a fiber to attract and hold molecules on its surface.
Properties of fibres and how to change them?
Material (chemical composition)
Nanostructure - crystallinity, order
Micostructure - length of nanofibres, order
bulk (spinning process temperature
surface
machanical modification
chemical modification
Yarn architecture
Material architecture
knitted / woven
different materials
Composition
What is the best t-shirt fabric?
100% cotton
Positive
Negative
· Soft
· Comfortable
· Breathable
· Gentle on the Skin
· Non-clingy (nicht anhaftend)
· Easily customized
· Popular
· Generally heavier
· Slow to dry
· Can be prone (Anfällig) to:
Shinkage & stains
Damage & wrinkles
Blends – Cotton / Poly
· Soft and comfy
· Lightweight
· More durable
· Better drape
· Less shrinkage
· Less wrinkling
· Quicker drying
· Can get a bit clingy
· Ca be irritating to some sensitive skin
· Sime higher prices
· Some minor restrictions on printing
100% Polyester
· Super durable
· Doesn’t shrink
· Doesn’t wrinkle
· Odor (Geruch) resistant
· Silky smooth drape
· Super quick drying
· Less breathable
· Can get very clingy (anhänglich)
· Synthetic feel
· Can irritate skin
· Restrictions on printing
· Some very high priced
Factors to consider when choosing a shirt fabric
performance
durability
cost
shrinkage + wrinkles
look and feel
enviromental impact
What is a biopolymer?
= naturally occurring polymer that is derived from living organisms
Examples of biopolymers include proteins, cellulose, chitin, and DNA (—> They can be either biodegradable or non-biodegradable, depending on their chemical composition and structure)
typically have lower environmental impact than synthetic polymers
What is the different between biopolymers and biodegradable polymers?
Biopolymers and biodegradable polymers are related terms, but they refer to slightly different concepts:
Biopolymers are polymers that are naturally occurring or derived from renewable sources such as plants or bacteria
Biodegradable polymers, on the other hand, are a specific class of polymers that can be broken down by natural processes into smaller molecules, such as carbon dioxide, water, or other naturally occurring substances.
—> So, while all biodegradable polymers are potentially biopolymers if they are derived from renewable sources, not all biopolymers are necessarily biodegradable.
What is a biodegradable polymer?
= specific class of polymers that can be broken down by natural processes into smaller molecules such as carbon dioxide, water, or other naturally occurring substances
Biodegradable polymers can be made from various materials, including synthetic or natural sources
examples of biodegradable polymers are polylactic acid (PLA), polyglycolic acid (PGA), and polycaprolactone (PCL)
bio decomposable
= products are compostable (destroyed by nature)
What is mean by green polymers?
= Polymers which are produced using green (sustainable) chemistry
Sustainability
= Meeting the needs of the present without compromising the ability of future generations to meet their own needs
insists on minimizing the adverse impact on the quality of air, water, and other natural resources to sustain the ecosystem’s
Textile industry is one of the major contributors (Hauptverursacher) of environment pollution (Umweltverschmutzung)
PLA
What is it?
What is its lifecycle?
PLA = polylactic acid —> biodegradable and compostable thermoplastic polymer made from renewable sources
Lifecycle:
made from renewable resources, which reduces its environmental impact compared to non-renewable plastics
During use, PLA can be used for a variety of applications (including packaging, disposable products, and 3D printing materials)
At the end of its lifecycle, PLA can be composting or recycling
When composted: it breaks down into natural compounds that can be used as fertilizers (Düngemittel)
When recycled: can be converted into new products
highly specialized shirt (black yak)
= highly technical fabrics —> use of 10 different materials (fabrics) Polyester, Polyurethane, Nylon, special trimmings
design for maximal performance, not comfort
maximum cooling (very hard workout)
specific details for maximum duarbility (cut proof areas, back,..)
—> shows, that with the bending of different materialsit is possible to creat new fabrics with special properties
test to examine the properties of fabrics
determination of specimen breakage (Bestimmung des Probenbruchs)
determination of mass loss (Beurteilung des Massenverlusts)
assessment of appearance changes (Beurteilung von Erscheinungsveränderungen)
Comparison of woven and knitted fabrics as well as Kevlar, PE and mixed fibers
focus on cut resistance
Woven fabrics tend to resist cuttimg action mire as compared to knitted fabric
cut indices values of woven fabrics are exceptionally high —> due to high strength and sompact structure
composite woven samples (Kevlar/PE) show highest cut resistance index compared to both pure kevlar and PE
cut resistance depends on the thickness of fabric —> by increasing thickness of fabric, the cut resistance property was increased
—> in sports wear woven composite fabrics —> due to superior cut resistance behavior
How does the fibre-shape influence the performance/properties for sports wear?
Surface area (Oberfläche):
impact its ability to wick (leiten) moisture and regulate temperature
Fibers with a larger surface area (such as microfibers) can more effectively wick moisture away from the skin, keeping the wearer dry and comfortable during exercise
Strength:
shape of a fiber can affect its strength and durability
Fibers with a circular cross-section (Querschnitt), such as nylon, tend to be stronger and more durable than fibers with an irregular shape, such as wool
Elasticity:
shape of a fiber can also influence its elasticity, or ability to stretch and recover
Fibers with a more irregular shape, such as wool, tend to be more elastic than fibers with a circular cross-section, such as nylon
Comfort:
shape of a fiber can also impact its softness and feel against the skin
Fibers with a round or smooth surface, such as polyester, tend to be softer and smoother against the skin, while fibers with an irregular shape, such as wool, can feel scratchy or itchy
what is the difference between knitted an woven?
—> Knitting and weaving are two different methods of producing fabrics from yarn
knitting = process of interlocking yarns together in a series of connected loops
strechy and flexible
weaving = process of interlacing two sets of yarns at right angles to each other
more structured and less strechy
—> main difference are their structure ans strechines
aspects of sports wear
material / mix
fabrics
design / combination
yarn
= long continuous length of interlocked fibers, suitable for use in the production of textiles, sewing (nähen), crocheting (Häkeln), knitting (stricken), weaving (weben), embroidery (nähen), or ropemarking (seilen)
composed of twisted strands of diber, which are known as plies when grouped together
micro fibers
fine diameter fibers
soft, durable, drapeable and high absorbency
used for high performance sport wear
e.g. nylon, polyester, acrylic and rayon
Hollow fibers
cross section is hollow
available shapes: round, trilobal and square (quadratisch)
resilient (belastbar), better recovery (bessere Erholung), bulky (voluminös)
better thermal insulation (by tapping air)
e.g. hollow polypropylene fibers
Bi-component fibers
consisted of two different polymers
provide thermal bonding, very fine fibers, unique cross section
have functions of special polaymers or additives
utilize (nutzen) each fibers advantages, which makes it easier to offset (ausgleichen) the drawbacks (Nachteile) of other fibers
amplify the performance in all respects, including aesthetics, comfort, cost and maintenance (wartung)
Whats the main criteria when it comes to choosing sports wear?
—> comfort
thermal comfort is determined by the movment of heat, moisture and air, is a large portiopn of the total clothing comfort
differences in thermal conductivity between differen shapes of the fibers
increase with hollow fibers in comparison to solid ones
tirlobal fibers had lower thermal conductivity and thermal absoption than round shapes because of the more compact yarn structure
wicking fiber
= wicking fabric uses a high-tech fiber composed of four and six-channel polyester fibers
improve capillary attraction and moisture transfer
provid a greater surface area for the liquid to flow across, resulting in improved wicking ability and quicker drying
ability of fabric to wick away sweat from the body is critical for wearers comfort
therms used for assesing fibre performance
Absorbency
Wicking
absorption
adsorption
moisture regain
hydrophilic
hydrophobic
water vapour transmission
automatic fabric abrasion & pilling tester
—> Martindale —> is a process that determines the abrasion resistance and thus the durability of fabrics
is a unit for quantifying the abrasion resistance of textiles
1) Determination of specimen breakage (Bestimmung des Probenbruchs)
Sample under a certain load and plane motion in Lissajous curve abrasion with abrasive, determine the wear-resisting ability of fabric as the Total abrasion times when sample damage
2) Determination of mass loss (Bestimmung des Massenverlusts)
Sample under a certain load and plane motion in Lissajous curve abrasion with abrasive, determine the wear-resisting ability of fabric as the mass loss of sample after abrasion a certain time
3) Assessment of appearance changes (Beurteilung von Erscheindungsveränderungen)
SampleunderacertainloadandplanemotioninLissajouscurveabrasive,determine the wear-resisting ability of fabric as the appearance changes of the sample
how is tensile strength, youngs modulus ans strain measured?
measure of a material's resistance to breaking under tension
most common method for measuring tensile strength is a tensile test, also known as a pull test or tension test
sample of the material is clamped at both ends and pulled in opposite directions until it breaks
force required to break the sample is recorded, and the tensile strength is calculated by dividing the maximum load by the cross-sectional area of the sample
how is the biodegradability measured?
biodegradability of a material can be measured in various ways depending on the specific material and conditions
In general, biodegradability testing involves measuring the rate and extent to which a material breaks down into natural substances, such as water, carbon dioxide, and biomass, under controlled conditions
define biodegradability
= ability of a substance to be broken down into simpler compounds by the action of living organisms such as bacteria, fungi, and algae in the environment
A biodegradable substance can be consumed by microorganisms and converted into natural substances such as carbon dioxide, water, and biomass, which do not harm the environment
rate of biodegradability and the extent to which a substance is biodegradable can vary depending on the chemical composition and environmental conditions
Fibers
Natural
plant
hair
animal
man made
cellulose
synthetic
polymers
cotton
= natural fiber —> plant —> cotton
50% of the worlds textile fiber
genetically modified for resistance to glyphosate
single-sell filaments
Properties: softness, breathability, durability
Use: textile products
Sports weare: often blenden with other fibers (like polyester) —> popular choice for t-shirts, sweatshirts, shirts
limitations: tends to retain moisture, which can lead to discomfort and chafing (Scheueren), praticulary during high-intensity activities
pro and cons of cotton (e.g. t-Shirt)
pros and cons of a t-shirt consits of cotton and Poly
Flax
= natural fiber —> plant —> flax
often referred as “linen”
Properties: strong, durable fiber that is absorbent and quick-drying, super hypoallergenic
Use: colthing and bedding
Sports wear: highly absorbent making it a good choice for sweatbands
soy fibers
= natural —> plant —> protein found in soybeans
Properties: soft and smooth texture —> comfortable to wear, leightweight and breathable, moisture-wicking properties
Use: clothing (often combined with other fibers)
Hair
= natural —> hair
cuticle consists of several layers of flat, thin cells, laid out overlapping one another as roof shingles (Dachziegel)
the cortex, which contai ns the kreation bundle sin cell structures, remain roughly rod-like (etwa stabförmig)
the medulla is a disorganized and open aera at the fibers center
people with straight hair = round hair fibers
people with wavy / curly hair = oval and other shaped fibers
Wool
= natural —> hair —> sheep
protein based fiber
crimped (gekräuselt) and naturally elastic, which allow them to spun into yarns that can be woven or knitted into variety of fabrics
came in a range of quality
properties: warm, moisture-wicking. dighly durable, withstand heavy wear and tear, helps to stay warm wehn its cold and cool when ist hot
Use: warm clothing such as sweaters, hats and gloves
sports wear: often used in baselayers and midlayers for cold-weather sports (skiing, snowboarding, mountaineering)
wool fibers have a natural ability to neutralize odors, which make it a good choice for sport wear that worn for extended periods of time
meriono wool, in practicular, i a popular choice for active wear due to its softness and high performance
Limitations: felting shrinkage (verfilzung)
whats the problem of wool?
—> felting shrinkage (verfilzung)
occurs during wet processin
scale edge of one fiber locks into the inter-scale gap of another fiber like a “ratchet” mechanism
fibers inerlock and connot return to their original positions
wool fibers can be made shrink-resistan either by removing or covering the scales or by restricting movments of fibers
meriono wool
= natural —> hair —> wool —> meriono sheep
type of wool that comes from the merione sheep
finer and softer than traditional wool fibers —> more comftortable to wear
surface of traditional wool fibers and merino wool differ in their texture and fiber diamter:
traditional = lager diameter and rougher surface
merino = smaller diameter and smoother surface
natural crimp, which provides elasticity and helps the wool to bounce after being streched
Properties: excellent warmth-toweigth ration, breathable, moisture-wicking
Use: clothing, socks
Sports wear: base layers, leggings, outdoor activities
silk
= natural —> animal —> silk
natural protein fiber
good wicking ability and can absorb water up to one.third its weight without feeling wet
high thermal conductivity (leitfähigkeit) and feels cool to the touch
Properties: strength, durability, mosture-wicking —> comfortable to wear in warm and cold weather, hypoallergenic, less likely to irritate the skin
Use: high-end clothing, accessories such as suits, dresses..
Sports wear: base laysers (help to regulate the body temperature and keep the wearer comfortable)
QMILK
= type of biopolymer fiber made from milk protein (casein)
produced extracting casein protein from milk and then processing it into fibers
100% natural, soft and smooth as silk and skin friendly
natural antibacterial effect and high hydrophilicity
only natural fiber which has thermo-bonding properties
light wight construction remain 100% and can be composted
Properties: soft, breathable, moisture-wicking, thermo-bonding, sustainable
sustainable because they are biodegradable and made from renewable resources
Use: textiles and clothing
How is casein extracted from milk?
extraction of raw material —> milk is first dewaterd and skimmed (abgeschöpft) —> casien obtained by acid treatment of skimmed milk
Polymerization —> casein is dissolved in sodium hydroxide
spinning —> wet spinning technique
hardening
washing
drying (avoid high temperatures)
ironing
Cellulose
—> man made
= the main component of plant cell walls and thus the most common organic compound in nature
lang-chain polymer made up of repeating units of glucose, a type of sugar
formed by the reaction if many glucose molecules with the elimination of water
cellulose fibers typacally extracted from these sources using a chemical or mechanical process:
cellulose carbohydrates
cellulose wood
cellulose cotton
pure cellulose is nit suitable for use in tectiles or other products without sime from fo chemical processing —> therfore regenerated fibers from cellulose = man made
viscose = rayon
= man made —> cellulose —> viscose /rayon
first man made synthetic fiber
cellulose fiber that is made from natural sources, such as wood or other plants materials
Properties: highly absrobent, washable, soft, smooth, comfortable
use: textile products, clothing, bedding
sports wear: less commonly used in sports wear due to their tendency to shrink and lose shape when wet
can be blendet with other fibers to improve its moisture.wicking properties
lyocell = tencel
= man made —> cellulose —> lyocell / tencel
a type of rayno
cellulose fiber that is produced fromm wood pulp using a closed-loop manufacturing process —> therfore cellulose in high purity with little hemicellulose and no lignin
no use of harmful carbon sulfilde
expensive ro produce
Properties: strength, durability, softness, eco-friendly
Use: clothing, bedding and other textiles
sports wear: often used because of their strength, durability and moisture-wicking properties
often blended witch other materials such as polyester to enhance their properties and increas their durability
modal
= man made —> cellulose —> modal
cellulose fiber that is derived from beech tree pulp
Properties: more lightweight than viscose, more breathable, highly resistant to pilling, silky smooth to the touch (softness), 50% more water-absorbent per unit volume than cotton
use: clothing and home textiles (towels, sleepwear, underweat..)
sports wear: soft and comfortable against the skin —> leggigs, tank tops, sport bras
what ist the difference between man man and synthetic fibers?
Man-made fibers are produced from natural materials, but are processed and spun into fiber form by humans (like rayon, acetate, and lyocell, which are made from cellulose, a natural material derived from plants)
Synthetic fibers are entirely man-made and do not use natural materials as their starting point. Examples of synthetic fibers include polyester, nylon, and acrylic, which are made from petrochemicals and other synthetic materials.
In general, synthetic fibers are known for their strength, durability, and resistance to wrinkles and shrinking, while man-made fibers often have a softer feel and better breathability.
synthetic fibers
= fibers thatare produced from various materials using chemical processes
created by extruding fiber-forming materials through spinnerets, forming a fiber —> synthetic or artifical fibers
made from sxnthetic polymers or small molecules —> created by polymerization (involves combining monomers to make a lang chain or polymer)
can created specific properties
synthetic fibers often used as a substizute for natural fibers in textiles and other products, due to their durability, strength and versatility (vielseitigkeit)
polyamide
= synthetic —> polyers —> polaymide
= water-repellent and resistant plastic —> because of the properties of polyamide, they are processed into snthetic fibers like nylon, perlon, enkalon
basic module are carbon atoms
Production: polycondensation, polymerization
fibers can be fine als well as corase, matt or shiny, abrasion reisistance (Abrieb)
fibers used in clothing, industrial materials and sports equipment
Nylon
= synthetic —> polymer —> polyamide —> nylon
synthetic polyamid fiber (substitute fir silk)
made by reaction of adipic and hexamethylenediamine, which creates a polymer that can be spun into fibers
ecological model studen —> minimal impact on the environment
produced by wsted products taht are unavoidable in oil production —> not biodegradable, but recycled —> possible to buy fully recycled nylon fabrics
Propeties: straong, durable, reisitant to abrasion, lightweight, easy to wasch an dry, resist shrinkage and wrinkle, waterproof, cost-effective but can sprak due to static charge, low absorbency, melt if catches fire
Use: toothbrush bristles, fishing lines, cloting —> often bend with other fibers to create strechy and comfortable fabrics
sports wear: athletik shirts, shorts, leggins
Polyester
= synthetic —> Polymers —> polyester
= incredibly strong (durable) —> dont tear (zerreisen), strech or pill (fusseln) easily like cotton and other natural fibers
synthetic polymer made from petroleum-derived chemicals
properties: strong, lightweight, retains it shape, resistant to wrinkles and shrrinking, moisture resistance, remain stain-resistance (schmutzabweisend), less breathable —> if you sweat the fabric will trap in the moisture and male you fell hot ans sticky, coarse —> dosnet have luxuriouse feel unlike many natural fabrics blended
use: clothing, bedding, durability made it especally popular for outdoor clothing
sports wear: quick-drying and misture-wicking making them a popular choice for sports and outdoor clothes
pro and cons of thirts consists of polyester
zylon fibers
= synthetic —> polymer
made from PBO —> produced by a dry-jet wet spinning process (diffucult to manufacture and expensive)
Properties: exceptional strength, heat resistant, low weigth, resistant to heat and chemicals, very low flammability, can degrade over time when exposed to UV light —> can result in a loss of strength and durability
use: tennis racquets,
sports wear: use for bullet proof vests and expensive sports wear
Polybenzimidazole fibers
= synthetic —> polymers
made from condensation of aromatic diamines with terephathalic acid or its derivatives —> resulting polymer is then spun into fibers ursing a dry-jet wet spinning process
stronges manmade organic fiber: almost twice as strong as aramid fibers (kevlar, Nomex) and about 10 times stronger than steel
100°C higher decomposition temperatur than aramid and exhibits very little creep under stress
properties: highly resistant to thermal degragation and maintaining their mechanical properties even at very high temperatures, high tensile strength, abrasion resistance, chemical resistance
use: protective clothing for firefighters, high temperatur protective gloves
sports wear: not commonly used in sports wear because of their relatively high cost and lack of breathability
However, they have been used in some specialized applications where extreme heat and flame resistance are required, such as in protective equipment for race car drivers
Dyneema fibers
made from polyethylene with a ultra high molecular weight
15xstronger than steel
Properties: exceptional strength and durability, low weight, resistant to abrasion, cutting and impact
use: protective gear, ropes
sports wear: climbing ropes, asiling ropes as well as in protective gear such as helemts, gloves and shoes
low weight, which makes them ideal for applications where weight is a critical factor, such as in sports where athletes need to move quickly and efficiently
combined with a protective baselayer, Dyneema offers cyclists effective abrasion protection at speeds up to 60 km/h, whilst also reducing the severity of open wounds at even higher speeds
Lycra, Spandex, Elastan
= essentially the same
elastic fiber made from a synthetic polymer called polyurethane
elastomer —> can be streched to a certain degree and it recoils when released
Properties: strechable, durable, resistant to damage from chemicals and heat
Use: clothing
sports wera: due to their abilility to provide comfortable and flexible support —> leggings, compression shorts, sport bars, swimsuits
provide a comfortable and snug fit (gute passform), which is essentail for activities that require a wide range of motion, such as yoga, dance and athletics
Polyurethane
= synthetics —> polymer
produced from a wide range of starting materials (monomers) and is therfore a class of polymers, rather than a distinct compound (deutliche verbindung)
contain two typs of monomers, which polymerize one after the other, so they are classed as alternating copolymers
can be formed into a range of materials with different properties —> used to make foams, adhesives, coating and synthetic fibers
Properties: changes depending on the composition, common pronlem if crumble due to hydrolysis
use: changes depending on the composition
sports wear: often used as a coating or as a component of composite materials to enhaunce durability, water resistance and breathability —> e.g. polyurethance coatinings can be applied to fabrics to create waterproof and breathable membrans for use in rain jackets, ski pants and other outdoor gear
neoprene
synthetic rubber material
typo of polymer known as chloroprene, which is created by the polymerization of chloroprene
Properties: excellent chemical resistance, good weatherability (witterungsbeständigkeit), high level of water resistance, good resistance to erbrittlement (Versprödung), ozon attack
use: wetsuits, gloves, protective clothing
sports wear: protectiv gear such as knee and elbow pads, · neoprene can be used in the design of clothing that is intended to provide compression and support for the muscles, such as compression shirts and shorts
Silicone
= is a name of a group of synthetic polymers
made up of silicopn, oxygen, carbon and hydrogen
can be found in main forms, including solids, liquids and gels
sports wear: used in form of coatings or prints on fabrics to provide slip-resistant or water resistant properties
e.g. silicone can be applied to the soles of socks or gloves ti improve traction or to the surface of swim caps to reduce drag in the water
GORE-TEX
= fabric made frin expanded polyetetrafluoroethylene (ePTFE), a synthetic material that is highly resistant to water and wind, bit allows moisture capor to pass through
material used in GORE-TEX is made up of billiopns of tiny pores, which are small enough to prevent water dropelts from passing through, but large enough to allow water vapor (i.e. sweat) to escape —> GORE-TEX is both waterproof and breathable, helping to keep the wearer dry and comfortable even in wet or humid conditions
clothes are made from three layers
conventional outer shell fabric
two seperate GORE-TEX layers with similar but quite different waterproof-breathable properties
explain the different layers from GORE-TEX
—> three layers
inside layer:
Thin, relativly delicate inner membrane of flim thats hydrophilic —> allows water vapor to escape but dosent allow liquid water in
hydrophilic layer absorbs perspiration produces by your body and transport it to the outside: water move becuase of the difference in water concentraion between the inseide and the outside
outer layer:
made from a microporouse playtic polymer (teflon)
hydrophobic —> resist water from outside, even wehen its impacting at high speed or pressure
hydrophobic layer doesent soak up water coming in from the outside, but allow perspiration to escape from the inside by diffusion
Nylon 66
= type of polyamide or nylon
Nylon 66 is made of two monomers each containing 6 carbon atoms
the monomers: hexamethylenediamine and adipic acid
aside from its superior physical characteristics, nylon 66 is attractive because its precursors are inexpensive
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