Disperse system is formed of
a substance that is distributed (dispersed phase) in the dispersing agent
classification of dispersed systems based on the
nature of interaction between dispesed phase and dispersion medium
-> hydrophilic colloids
-> hydrophobic colloids
Colloid dispersed systems:
determination by colloidal composition
Dispersed colloids
association colloids
macromolecular colloids
Macromolecular colloids
Emulsion
two fuids that dont mix
unstable
Emulsifiers
stabilize an emulsion
in the gi tract its vile acids
emulsifier for oil in water
must be hydrophilic (soap)
Gels
in more concentrated solutions aome hydrophilic colloids harden into a gel mass
have a net like structure
properties of colloids
OPTICAL- Tyndall effect, the light scatters
MECANICAL- brownian movement, zigzag path
DIALYSIS- colloid particles can not pass through the cellophane or animal bladder (purification of proteins)
ELECTRICALLY- colloid particles obtain charge in a polar solvent (H2O)
ELECTROPHORESIS- movement of charged colloidal particles in an electric field
ADSORPTION- sponatneous accumulation of a one subastance (adsorbate) on the other substance (adorbent) -selctive
-rapid
spontaneous and followed by the decrease of entropy
-usually exotherm
Physical adsorption
weak bond
reversible
chemical adsorption
a chemicla bond is created
rearly reversible
slower than physical adsorption
Adsorption
usually the adsorbens is solid substance which adsorbs gases or substances from solution
amount of adsorbed substance depends on
nature of the substance
specific surface of the adsorbent
absorbate concentration (pressure)
Donnan equilibrium
occures when the solution with macromolecules is seperated by semipermeable membreane from pure solvent or a solution with small ions
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