Material Extrusion (MEX)
Definition
Type of Material
State of Fusion
Material Distribution
Basic AM principle
Produced by AM
Consolidation by secondary step
Definition:
AM process in which material is selectively dispensed through a nozzle or orifice (Öffnung)
Type of Material: Composite (metall filler + polymer binder)
State of Fusion: thermal reaction bonding
Material Distribution: Depostion Nozzle
Basic AM principle: Extrusion of melted material
Produced by AM: Greenbody
Composite material part joined by Polymeradhesion
Consolidation by secondary step: Furnace Sintering
Advantages/ Limitations of Material Extrusion (MEX)
+easy to use
+equipment usually not expensive
+variety of materials
-Need of support structures
-high surface roughness compared to other AM techniques
-Anisotropy of properties
Extrusion Mechanisms in MEX:
Plunger-based:
plunger (Kolben) pushes pre-heated Melt through an Orifice
Filament-based:
rotating gears (Zahnrad) push a filament through a heated nozzle
Screw-based:
rotating screw (Schraube) melts and mixes materials before deposition through nozzle
MEX:
Process Flow steps
-MEX:
AM Steps:
Feed stock material gets heated
Fusion/ Melting
Extrusion and cooling after deposition
Solidification
Secondary Steps:
Green part / body
furnace sintering
Consolidation (Verdichtung)
MEX - Feedstock Material
Binder Systems: polymeric component
Main binder Component:
50-90% of the Volume
removed first during debinding step
Backbone:
0-50% of the Volume
holds together shape of the greenpart when main binder is removed
thermally decomposes right before sintering begins, just as powder particles start fusing together
Additives:
1-10% of the volume
ensure uniform distribution of filler powder throughout the binder matrix
preventing agglomeration and phase seperation
Fillers
MEX - Feedstock Material: Fillers
Ceramic fillers:
Silicon nitrate
Titanium dioxide + MgO
Metall fillers:
Stainless steel
Titanium
MEX - processability of filaments depends on:
mechanical properties of the filament
flow properties of feedstock
processing conditions
geometry of the filament
design of printing head
MEX Filamentextrusion Risk:
Buckling (Nachgeben) of the filament
Extrusion pressure > critical buckling stress
Risk area of buckling:
MEX - Processparameters:
concept models:
.STL File
Unprocessed Material:
Mechanical Properties
Density
System:
Nozzle temperature
Nozzle diameter
Envelope temperature (Bauraumtemperatur)
Wear resistancy (Verschleißfestigkeit) of extruder
Environmental factors:
Humidity
Temperature
Build orientation:
x-/ y-/ z-direction
Working parameters:
contur width
part x/y/z-shrinkage factor
layer thickness
raster width
air gap
raster angle
Build orientation
bead width
layer/ slice thickness
Direction along part is grown (typicall z-direction)
Bead width:
width of extrusion track; 0.3-1mm
layer slice thickness:
height of ectrusion track; (z-direction)
MEX -Processparameters:
Contouring
Raster Orientation & Angle
Air gap
Contouring:
extrusion tracks along the part edges; 1-2
Raster Orientation:
The angle/direction at which the internal infill extrusion tracks are deposited relative to the main axis
Air gap:
space between two extrusion tracks of the same layer
default = 0; tracks just touch
positive gap: tracks dont touch/ rapid build
negative gap: tracks do overlap/ dense structure
Nozzle or liquefier temperature
Envelope temperature
Feed rate / speed
Nozzle or liquefier temperature:
Equals melt temperature at the exit of the tip of the nozzle
Envelope temperature:
temperature of air / room temperature
Feed rate/ speed:
speed at which filament is driven into the liquefier
Extrusion rate
Travel speed
Extrusion rate:
length of volume extruded in given time interval
Travel speed:
speed of moving print head
MEX - Debinding:
definition
occuring errors
debinding techniques
Debinding:
The removal of the main primary binder system (polymers/waxes) prior to sintering
Occuring error:
Bloating (Aufblähung)
Blistering (Blasenbildung)
Surface Cracking
Large Internal voids (Porosity)
debinding techniques:
thermal
solvent
catalytic
MEX - Sintering:
mechanism
temperature range
final heat treatment that transforms powder particle of the brown body into bulk material (solid part)
Mechanism:
growing sintering necks between particles, leads in reduction of porosity and overall part shrinkage
Temperature range:
below melting point of main metals
typicall around 70-90% melting point temperature of main metals
Which of the following statements about Material Extrusion with highly filled polymers is wrong?
1. The binder system in Material Extrusion of highly filled polymers consists of a solvable binder, a backbone polymer, and additives.
2.The highest possible degree of filling leads to particularly dense parts after sintering and has no effect on the printing process.
3. Whether buckling occurs is defined by the geometric dimensions of the nozzle (including feeding system) and material properties.
4. The sintering of the components serves to remove the polymer and takes place below the melting temperature of the filler.
5. The shrinkage of the components depends on the printing direction
Wrong is:
2
4
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